It's best to use all AGMs or all wet cells but if you have one of each and need the extra power you can mix them. Wet batteries rest at a slightly lower voltage than dry batteries so when the vehicle is not running, the wet battery will leach the surface charge from the AGM and the long term result will be slightly shorter life for the AGM battery. It won't be catastrophic though so if you need to mix them for a few months it's not a problem. And yes, you can use AGM batteries as starting batteries.
As grounds go, it really depends on the vehicle. Many manufacturers are using epoxy adhesives to glue body panels together these days, in lieu of welding, so if you have a late model unibody car there is a pretty good chance that you don't have a good ground path for a rear battery bank. If you don't know if the manufacturer of your car used epoxies or spot welds, your best bet is to run a separate ground to your rear battery(s). And obviously, if you have a
vehicle with a frame, that's a safe ground.
Another thing to keep in mind with rear battery banks is that big three grounds in the front can cause the rear batteries not to get sufficient charge current so that wiring (if installed) needs to be changed when you add them. Ideally, you want a 1/0 + and - wire from the alternator to the front battery and then from there you run one (or more) + & - wire to the rear battery bank. If you have multiple batteries in the rear you ground only the last one in the circuit to the frame/body as this ensures the best and most complete path for charging current.
In simple terms, current follows the path of least resistance.