You turn your nose up at the amount of work it would take to fiberglass the roof, but then agree to this idea of making individualized roof braces out of wood that will need to be adhered to the roof anyway? Seems like coating an old tee-shirt in resin, and then rollering it to your roof, would be a much simpler project than making all those custom braces. But to each their own.
But if you must use the wooden brace method, plywood is much stronger than mdf laterally, and will do the job much better.